Silica Chloride Mediated Alkylation of Electron-rich Aromatics by Benzyl or tert-Butyl Chloride

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Deprotection of Benzyl and t-Butyl Phosphate, Phosphite, and Sulfite Esters by Silica Chloride

Deprotection of phosphate, phosphate, and sulfite esters by silica chloride is described. Silica chloride is a mild, selective, and effective reagent for cleavage of benzyl and t-butyl esters of the above compounds.

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deprotection of benzyl and t-butyl phosphate, phosphite, and sulfite esters by silica chloride

deprotection of phosphate, phosphate, and sulfite esters by silica chloride is described. silica chloride is a mild, selective, and effective reagent for cleavage of benzyl and t-butyl esters of the above compounds.

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CLEAVAGE OF ESTERS AND ETHERS WITH SILICA CHLORIDE

Silica chloride converted benzyl or tert-butyl esters to the corresponding acid chlorides and alkyl chlorides. It also converted benzyl or tert-butyl phenyl ethers to the corresponding allcyl chlorides and phenol

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N-Benzyl-N-methyl­morpholinium chloride

In the title compound, C(12)H(18)NO(+)·Cl(-), the cations and anions are inter-connected by weak C-H⋯Cl hydrogen bonds. The morpholine ring system adopts a chair conformation.

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N-Benzyl-N-ethyl­morpholinium chloride

In the crystal structure of the title compound, C(13)H(20)NO(+)·Cl(-), the morpholine ring is in a chair conformation and the mol-ecules are linked by weak inter-molecular C-H⋯Cl hydrogen bonding.

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ژورنال

عنوان ژورنال: Bulletin of the Korean Chemical Society

سال: 2010

ISSN: 0253-2964

DOI: 10.5012/bkcs.2010.31.10.3038